Nonclassical oxygen atom transfer reactions of oxomolybdenum(VI) bis(catecholate).
نویسندگان
چکیده
Mechanistic studies indicate that the oxomolybdenum(vi) bis(3,5-di-tert-butylcatecholate) fragment deoxygenates pyridine-N-oxides in a reaction where the oxygen is delivered to molybdenum but the electrons for substrate reduction are drawn from the bound catecholate ligands, forming 3,5-di-tert-butyl-1,2-benzoquinone.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 63 شماره
صفحات -
تاریخ انتشار 2012